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{"news_id":9072,"is_preview":0,"news_info":{"id":9072,"company_id":176,"user_id":411,"author":"","website_id":781,"pub_date":"2024-09-03 11:01:04","urla":"phenolic-resin-spherical-activated-carbon-preparation","description":"This article details the preparation methods, mechanisms, and performance characterization of phenolic resin-based SAC, and analyzes its current applications and future prospects.","image_url":"https:\/\/oss.matchpages.cn\/matchpages\/common\/2024\/0424\/9899\/66287284daf5b\/%E7%90%83%E7%82%AD--1---1---1-.webp","image_alt":"Spherical Activated Carbon","title":"Preparation, Characterization, and Applications of Phenolic Resin-Based Spherical Activated Carbon","content":"<h3 style=\"line-height: 1.75;\"><span style=\"font-size: 18pt; color: #000000;\"><strong>Preparation, Characterization, and Applications of Phenolic Resin-Based Spherical Activated Carbon<\/strong><\/span><\/h3>\n<h2 style=\"line-height: 1.75;\"><span style=\"font-size: 14pt; color: #045e14;\"><strong>Introduction<\/strong><\/span><\/h2>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Spherical activated carbon (SAC) is classified into three main categories based on the precursor materials used: coal-based, pitch-based, and resin-based SAC. Each type has its own characteristics and applications. Phenolic resin-based SAC is particularly notable for its high carbon content, minimal ash content, uniform molecular structure, and straightforward production process.<\/span><\/p>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Phenolic resin is one of the earliest synthetic resins, known for its wide availability, low cost, high mechanical strength, and excellent heat resistance. Activated carbon derived from phenolic resin is cost-effective, exhibits high carbonization yield, and offers superior adsorption capabilities compared to other types of activated carbon.<\/span><\/p>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">This article details the preparation methods, mechanisms, and performance characterization of phenolic resin-based SAC, and analyzes its current applications and future prospects.<\/span><\/p>\n<h2 style=\"line-height: 1.75;\"><span style=\"font-size: 14pt; color: #045e14;\"><strong>Preparation Methods and Mechanisms of Phenolic Resin-Based Spherical Activated Carbon<\/strong><\/span><\/h2>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">The preparation of phenolic resin-based SAC involves three critical processes: preparation of phenolic resin spheres, carbonization, and activation.<\/span><\/p>\n<h3 style=\"line-height: 1.75;\"><span style=\"font-size: 12pt; color: #000000;\"><strong>1. Preparation of Phenolic Resin Spheres<\/strong><\/span><\/h3>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">There are several methods for preparing phenolic resin spheres, each with its own advantages and disadvantages:<\/span><\/p>\n<table style=\"border-collapse: collapse; border-color: #7E8C8D; border-style: solid;\" border=\"1px\">\n<thead>\n<tr>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Method<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Characteristics<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Advantages<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Disadvantages<\/strong><\/span><\/td>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Suspension Polymerization<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">\"Water-in-oil\" system; requires dispersants, curing agents, and mechanical stirring; produces large particles with varying sizes.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Low cost, safe, and easy separation; low viscosity; stable product quality.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Can lead to reaction failure due to auto-acceleration; difficult to remove dispersants; currently cannot be produced continuously in industry.<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Reverse Suspension Polymerization<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">\"Oil-in-water\" system; requires dispersants, dispersing medium, initiators, and mechanical stirring; product molecular weight controlled by initiator amount.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Good heat conductivity; easy removal of reaction heat; low viscosity; stable product quality.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Similar challenges as suspension polymerization; cannot be produced continuously in industry.<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Emulsion Polymerization<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">\"Water-in-oil\" system.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Few impurities.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Requires crushing and sieving of resin.<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Precipitation Polymerization<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Monomer and initiator dissolved in medium; polymer precipitates as reaction progresses.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Smooth spheres, uniform particle size, low viscosity.<\/span><\/td>\n<td style=\"border: 1px solid #95a5a6;\"><span style=\"color: #34495e; font-size: 10pt;\">Toxic solvents and low yield.<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p style=\"line-height: 1.75;\"> <\/p>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Suspension polymerization is frequently used due to its simplicity and ability to produce microspheres with good sphericity without the need for crushing and sieving.<\/span><\/p>\n<h3 style=\"line-height: 1.75;\"><span style=\"font-size: 12pt; color: #000000;\"><strong>2. Carbonization of Phenolic Resin Spheres<\/strong><\/span><\/h3>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">The carbonization process involves heating the phenolic resin spheres to remove non-carbon elements (such as oxygen, hydrogen, and nitrogen), resulting in a carbon-rich product. This process typically occurs in three stages:<\/span><\/p>\n<ul style=\"line-height: 1.75;\">\n<li><span style=\"color: #000000;\"><strong>Stage 1 (Room temperature to 250°C):<\/strong> Dehydration and initial reactions occur.<\/span><\/li>\n<li><span style=\"color: #000000;\"><strong>Stage 2 (250°C to 400°C):<\/strong> Resin molecular chains break, leading to resin disintegration.<\/span><\/li>\n<li><span style=\"color: #000000;\"><strong>Stage 3 (400°C to 800°C):<\/strong> Carbon atoms undergo cyclization and aromatization, forming carbon-rich solid pyrolysis products with increased graphite microcrystals.<\/span><\/li>\n<\/ul>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">The carbonization process significantly affects the pore structure and specific surface area of the final product.<\/span><\/p>\n<h3 style=\"line-height: 1.75;\"><span style=\"font-size: 12pt; color: #000000;\"><strong>3. Activation of Phenolic Resin Spheres<\/strong><\/span><\/h3>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">After carbonization, the phenolic resin spheres have some porosity, but further activation is required to enhance the specific surface area and adsorption properties. Activation methods include physical and chemical activation:<\/span><\/p>\n<table style=\"border-collapse: collapse; border-color: #34495E; border-style: solid;\" border=\"1px\">\n<thead>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Method<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Activation Temperature<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Equipment Requirements<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Corrosion to Equipment<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Environmental Impact<\/strong><\/span><\/td>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Physical Activation<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">750°C - 1100°C<\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Simple<\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Low<\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Low<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Chemical Activation<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Below 750°C<\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Complex<\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">High<\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">High<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p style=\"line-height: 1.75;\"> <\/p>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Physical activation involves the use of gases like steam, oxygen, or carbon dioxide, while chemical activation uses chemicals like phosphoric acid, zinc chloride, or potassium hydroxide.<\/span><\/p>\n<h2 style=\"line-height: 1.75;\"><span style=\"font-size: 14pt; color: #045e14;\"><strong>Characterization of Phenolic Resin-Based Spherical Activated Carbon<\/strong><\/span><\/h2>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Key performance indicators for phenolic resin-based SAC include:<\/span><\/p>\n<ul style=\"line-height: 1.75;\">\n<li><span style=\"color: #000000;\"><strong>Average Particle Size and Sphericity:<\/strong> These determine the smoothness, rollability, and uniformity of the spheres, which can be measured using laser particle size analyzers and micrometers.<\/span><\/li>\n<li><span style=\"color: #000000;\"><strong>Carbonization Temperature and Post-Carbonization Performance:<\/strong> The carbonization temperature significantly influences the final structure and properties of the SAC, typically determined using thermogravimetric analysis (TG-DTG).<\/span><\/li>\n<li><span style=\"color: #000000;\"><strong>Specific Surface Area and Pore Structure:<\/strong> These are critical for adsorption performance, with larger surface areas and more developed pore structures being desirable. Nitrogen adsorption methods are commonly used for measurement.<\/span><\/li>\n<li><span style=\"color: #000000;\"><strong>Other Performance Metrics:<\/strong> Depending on the application, other tests such as CO2 adsorption capacity, charge-discharge performance, wear resistance, and biocompatibility may be conducted.<\/span><\/li>\n<\/ul>\n<p><span style=\"color: #000000;\"><img src=\"https:\/\/oss.matchpages.cn\/matchpages\/common\/2024\/0424\/9899\/66287284daf5b\/%E7%90%83%E7%82%AD--1---1---1-.webp\" alt=\"Spherical Activated Carbon \" width=\"600\" height=\"300\" data-resolution=\"1025*420\" \/><\/span><\/p>\n<h2 style=\"line-height: 1.75;\"><span style=\"font-size: 14pt; color: #045e14;\"><strong>Applications and Future Prospects of Phenolic Resin-Based Spherical Activated Carbon<\/strong><\/span><\/h2>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Phenolic resin-based SAC finds extensive <span style=\"text-decoration: underline;\"><span style=\"color: #236fa1; text-decoration: underline;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"activated-carbon-applications\" target=\"_blank\" rel=\"noopener\" data-page_id=\"19699\" data-page_name=\"Activated Carbon Applications \uff5c ACC\" data-page_type=\"menuPage\">applications<\/a><\/span><\/span> due to its excellent adsorption properties, biocompatibility, and electrical performance. Key application areas include:<\/span><\/p>\n<table style=\"border-collapse: collapse; border-color: #34495E; border-style: solid;\" border=\"1px\">\n<thead>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Field<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Application<\/strong><\/span><\/td>\n<\/tr>\n<\/thead>\n<tbody>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Environmental Protection<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Air pollution control, water treatment, SO<sub>2<\/sub> adsorption, radioactive material adsorption.<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Biomedical Applications<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Blood purification, oral adsorbents, drug delivery systems.<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Catalyst Supports<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Supporting nickel and palladium catalysts.<\/span><\/td>\n<\/tr>\n<tr>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\"><strong>Energy Storage<\/strong><\/span><\/td>\n<td style=\"border: 1px solid #7e8c8d;\"><span style=\"color: #34495e; font-size: 10pt;\">Electrochemical double-layer capacitors (EDLCs) with long service life, short charging times, and good safety performance.<\/span><\/td>\n<\/tr>\n<\/tbody>\n<\/table>\n<p style=\"line-height: 1.75;\"> <\/p>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">Moreover, phenolic resin-based SAC can be combined with other materials (e.g., metals, metal oxides) to create new functional materials with enhanced properties.<\/span><\/p>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">For more applications information:<\/span><\/p>\n<ul>\n<li style=\"line-height: 1.75;\"><span style=\"text-decoration: underline;\"><span style=\"color: #236fa1; text-decoration: underline;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"spherical-activated-carbon\" target=\"_blank\" rel=\"noopener\" data-page_id=\"19576\" data-page_name=\"Spherical Activated Carbon\uff5cACC\" data-page_type=\"menuPage\">Spherical Activated Carbon<\/a><\/span><\/span><\/li>\n<li style=\"line-height: 1.75;\">\n<div class=\"menu-text \">--<span style=\"text-decoration: underline;\"><span style=\"color: #236fa1;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"resin-based-spherical-activated-carbon\" target=\"_blank\" rel=\"noopener\" data-page_id=\"21460\" data-page_name=\"Resin Based Spherical Activated Carbon\" data-page_type=\"menuPage\">Resin Based Spherical Activated Carbon<\/a><\/span><\/span><\/div>\n<\/li>\n<\/ul>\n<h2 style=\"line-height: 1.75;\"><span style=\"font-size: 14pt; color: #045e14;\"><strong>Conclusion<\/strong><\/span><\/h2>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">In conclusion, phenolic resin-based spherical activated carbon offers significant advantages in terms of preparation and performance, making it highly promising for industrial development.<\/span><\/p>\n<hr \/>\n<p style=\"line-height: 1.75;\"><span style=\"color: #000000;\">For more information on other types of activated carbon:<\/span><\/p>\n<ul>\n<li style=\"line-height: 1.75;\"><span style=\"text-decoration: underline;\"><span style=\"color: #236fa1; text-decoration: underline;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"bamboo-based-activated-carbon\" target=\"_blank\" rel=\"noopener\" data-page_id=\"19595\" data-page_name=\"Bamboo Based Activated Carbon\uff5cACC\" data-page_type=\"menuPage\">Bamboo Based Activated Carbon<\/a><\/span><\/span><\/li>\n<li style=\"line-height: 1.75;\"><span style=\"text-decoration: underline;\"><span style=\"color: #236fa1; text-decoration: underline;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"wood-based-activated-carbon\" target=\"_blank\" rel=\"noopener\" data-page_id=\"19594\" data-page_name=\"Wood Based Activated Carbon\uff5cACC\" data-page_type=\"menuPage\">Wood Based Activated Carbon<\/a><\/span><\/span><\/li>\n<li style=\"line-height: 1.75;\"><span style=\"text-decoration: underline;\"><span style=\"color: #236fa1; text-decoration: underline;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"coconut-shell-based-activated-carbon\" target=\"_blank\" rel=\"noopener\" data-page_id=\"19605\" data-page_name=\"Coconut Shell Based Activated Carbon\uff5cACC\" data-page_type=\"menuPage\">Coconut Shell Based Activated Carbon<\/a><\/span><\/span><\/li>\n<li style=\"line-height: 1.75;\"><span style=\"text-decoration: underline;\"><span style=\"color: #236fa1; text-decoration: underline;\"><a style=\"color: #236fa1; text-decoration: underline;\" href=\"precious-metal-carrier-activated-carbon\" target=\"_blank\" rel=\"noopener\" data-page_id=\"19582\" data-page_name=\"Precious Metal Carrier Activated Carbon\uff5cACC\" data-page_type=\"menuPage\">Precious Metal Carrier Activated Carbon<\/a><\/span><\/span><\/li>\n<\/ul>\n<p style=\"line-height: 1.75;\"> <\/p>","discuss":0,"seo_title":"Phenolic Resin-Based Spherical Activated Carbon","seo_keyword":"Phenolic Resin-Based Spherical Activated Carbon,Spherical Activated Carbon Preparation,Activated Carbon Applications,Resin-Based Spherical Activated Carbon","seo_describe":"Learn about the preparation, characterization, and applications of phenolic resin-based spherical activated carbon. Discover its key features, benefits, and industrial applications","track_code":"","viewer":"","source_copy_id":0,"sort":17,"status":0,"data_time":"2024-09-03 14:29:16","create_time":"2024-09-03 10:27:30","update_time":"2025-04-02 09:56:43","type_items":[{"id":2083,"website_id":781,"name":"Activated Carbon","urla":""}],"tag_items":[]}}
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Preparation, Characterization, and Applications of Phenolic Resin-Based Spherical Activated Carbon
This article details the preparation methods, mechanisms, and performance characterization of phenolic resin-based SAC, and analyzes its current applications and future prospects.
<h3 style="line-height: 1.75;"><span style="font-size: 18pt; color: #000000;"><strong>Preparation, Characterization, and Applications of Phenolic Resin-Based Spherical Activated Carbon</strong></span></h3> <h2 style="line-height: 1.75;"><span style="font-size: 14pt; color: #045e14;"><strong>Introduction</strong></span></h2> <p style="line-height: 1.75;"><span style="color: #000000;">Spherical activated carbon (SAC) is classified into three main categories based on the precursor materials used: coal-based, pitch-based, and resin-based SAC. Each type has its own characteristics and applications. Phenolic resin-based SAC is particularly notable for its high carbon content, minimal ash content, uniform molecular structure, and straightforward production process.</span></p> <p style="line-height: 1.75;"><span style="color: #000000;">Phenolic resin is one of the earliest synthetic resins, known for its wide availability, low cost, high mechanical strength, and excellent heat resistance. Activated carbon derived from phenolic resin is cost-effective, exhibits high carbonization yield, and offers superior adsorption capabilities compared to other types of activated carbon.</span></p> <p style="line-height: 1.75;"><span style="color: #000000;">This article details the preparation methods, mechanisms, and performance characterization of phenolic resin-based SAC, and analyzes its current applications and future prospects.</span></p> <h2 style="line-height: 1.75;"><span style="font-size: 14pt; color: #045e14;"><strong>Preparation Methods and Mechanisms of Phenolic Resin-Based Spherical Activated Carbon</strong></span></h2> <p style="line-height: 1.75;"><span style="color: #000000;">The preparation of phenolic resin-based SAC involves three critical processes: preparation of phenolic resin spheres, carbonization, and activation.</span></p> <h3 style="line-height: 1.75;"><span style="font-size: 12pt; color: #000000;"><strong>1. Preparation of Phenolic Resin Spheres</strong></span></h3> <p style="line-height: 1.75;"><span style="color: #000000;">There are several methods for preparing phenolic resin spheres, each with its own advantages and disadvantages:</span></p> <table style="border-collapse: collapse; border-color: #7E8C8D; border-style: solid;" border="1px"> <thead> <tr> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Method</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Characteristics</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Advantages</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Disadvantages</strong></span></td> </tr> </thead> <tbody> <tr> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Suspension Polymerization</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">"Water-in-oil" system; requires dispersants, curing agents, and mechanical stirring; produces large particles with varying sizes.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Low cost, safe, and easy separation; low viscosity; stable product quality.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Can lead to reaction failure due to auto-acceleration; difficult to remove dispersants; currently cannot be produced continuously in industry.</span></td> </tr> <tr> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Reverse Suspension Polymerization</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">"Oil-in-water" system; requires dispersants, dispersing medium, initiators, and mechanical stirring; product molecular weight controlled by initiator amount.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Good heat conductivity; easy removal of reaction heat; low viscosity; stable product quality.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Similar challenges as suspension polymerization; cannot be produced continuously in industry.</span></td> </tr> <tr> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Emulsion Polymerization</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">"Water-in-oil" system.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Few impurities.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Requires crushing and sieving of resin.</span></td> </tr> <tr> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;"><strong>Precipitation Polymerization</strong></span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Monomer and initiator dissolved in medium; polymer precipitates as reaction progresses.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Smooth spheres, uniform particle size, low viscosity.</span></td> <td style="border: 1px solid #95a5a6;"><span style="color: #34495e; font-size: 10pt;">Toxic solvents and low yield.</span></td> </tr> </tbody> </table> <p style="line-height: 1.75;"> </p> <p style="line-height: 1.75;"><span style="color: #000000;">Suspension polymerization is frequently used due to its simplicity and ability to produce microspheres with good sphericity without the need for crushing and sieving.</span></p> <h3 style="line-height: 1.75;"><span style="font-size: 12pt; color: #000000;"><strong>2. Carbonization of Phenolic Resin Spheres</strong></span></h3> <p style="line-height: 1.75;"><span style="color: #000000;">The carbonization process involves heating the phenolic resin spheres to remove non-carbon elements (such as oxygen, hydrogen, and nitrogen), resulting in a carbon-rich product. This process typically occurs in three stages:</span></p> <ul style="line-height: 1.75;"> <li><span style="color: #000000;"><strong>Stage 1 (Room temperature to 250°C):</strong> Dehydration and initial reactions occur.</span></li> <li><span style="color: #000000;"><strong>Stage 2 (250°C to 400°C):</strong> Resin molecular chains break, leading to resin disintegration.</span></li> <li><span style="color: #000000;"><strong>Stage 3 (400°C to 800°C):</strong> Carbon atoms undergo cyclization and aromatization, forming carbon-rich solid pyrolysis products with increased graphite microcrystals.</span></li> </ul> <p style="line-height: 1.75;"><span style="color: #000000;">The carbonization process significantly affects the pore structure and specific surface area of the final product.</span></p> <h3 style="line-height: 1.75;"><span style="font-size: 12pt; color: #000000;"><strong>3. Activation of Phenolic Resin Spheres</strong></span></h3> <p style="line-height: 1.75;"><span style="color: #000000;">After carbonization, the phenolic resin spheres have some porosity, but further activation is required to enhance the specific surface area and adsorption properties. Activation methods include physical and chemical activation:</span></p> <table style="border-collapse: collapse; border-color: #34495E; border-style: solid;" border="1px"> <thead> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Method</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Activation Temperature</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Equipment Requirements</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Corrosion to Equipment</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Environmental Impact</strong></span></td> </tr> </thead> <tbody> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Physical Activation</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">750°C - 1100°C</span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Simple</span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Low</span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Low</span></td> </tr> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Chemical Activation</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Below 750°C</span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Complex</span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">High</span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">High</span></td> </tr> </tbody> </table> <p style="line-height: 1.75;"> </p> <p style="line-height: 1.75;"><span style="color: #000000;">Physical activation involves the use of gases like steam, oxygen, or carbon dioxide, while chemical activation uses chemicals like phosphoric acid, zinc chloride, or potassium hydroxide.</span></p> <h2 style="line-height: 1.75;"><span style="font-size: 14pt; color: #045e14;"><strong>Characterization of Phenolic Resin-Based Spherical Activated Carbon</strong></span></h2> <p style="line-height: 1.75;"><span style="color: #000000;">Key performance indicators for phenolic resin-based SAC include:</span></p> <ul style="line-height: 1.75;"> <li><span style="color: #000000;"><strong>Average Particle Size and Sphericity:</strong> These determine the smoothness, rollability, and uniformity of the spheres, which can be measured using laser particle size analyzers and micrometers.</span></li> <li><span style="color: #000000;"><strong>Carbonization Temperature and Post-Carbonization Performance:</strong> The carbonization temperature significantly influences the final structure and properties of the SAC, typically determined using thermogravimetric analysis (TG-DTG).</span></li> <li><span style="color: #000000;"><strong>Specific Surface Area and Pore Structure:</strong> These are critical for adsorption performance, with larger surface areas and more developed pore structures being desirable. Nitrogen adsorption methods are commonly used for measurement.</span></li> <li><span style="color: #000000;"><strong>Other Performance Metrics:</strong> Depending on the application, other tests such as CO2 adsorption capacity, charge-discharge performance, wear resistance, and biocompatibility may be conducted.</span></li> </ul> <p><span style="color: #000000;"><img src="https://oss.matchpages.cn/matchpages/common/2024/0424/9899/66287284daf5b/%E7%90%83%E7%82%AD--1---1---1-.webp" alt="Spherical Activated Carbon " width="600" height="300" data-resolution="1025*420" /></span></p> <h2 style="line-height: 1.75;"><span style="font-size: 14pt; color: #045e14;"><strong>Applications and Future Prospects of Phenolic Resin-Based Spherical Activated Carbon</strong></span></h2> <p style="line-height: 1.75;"><span style="color: #000000;">Phenolic resin-based SAC finds extensive <span style="text-decoration: underline;"><span style="color: #236fa1; text-decoration: underline;"><a style="color: #236fa1; text-decoration: underline;" href="activated-carbon-applications" target="_blank" rel="noopener" data-page_id="19699" data-page_name="Activated Carbon Applications ｜ ACC" data-page_type="menuPage">applications</a></span></span> due to its excellent adsorption properties, biocompatibility, and electrical performance. Key application areas include:</span></p> <table style="border-collapse: collapse; border-color: #34495E; border-style: solid;" border="1px"> <thead> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Field</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Application</strong></span></td> </tr> </thead> <tbody> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Environmental Protection</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Air pollution control, water treatment, SO<sub>2</sub> adsorption, radioactive material adsorption.</span></td> </tr> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Biomedical Applications</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Blood purification, oral adsorbents, drug delivery systems.</span></td> </tr> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Catalyst Supports</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Supporting nickel and palladium catalysts.</span></td> </tr> <tr> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;"><strong>Energy Storage</strong></span></td> <td style="border: 1px solid #7e8c8d;"><span style="color: #34495e; font-size: 10pt;">Electrochemical double-layer capacitors (EDLCs) with long service life, short charging times, and good safety performance.</span></td> </tr> </tbody> </table> <p style="line-height: 1.75;"> </p> <p style="line-height: 1.75;"><span style="color: #000000;">Moreover, phenolic resin-based SAC can be combined with other materials (e.g., metals, metal oxides) to create new functional materials with enhanced properties.</span></p> <p style="line-height: 1.75;"><span style="color: #000000;">For more applications information:</span></p> <ul> <li style="line-height: 1.75;"><span style="text-decoration: underline;"><span style="color: #236fa1; text-decoration: underline;"><a style="color: #236fa1; text-decoration: underline;" href="spherical-activated-carbon" target="_blank" rel="noopener" data-page_id="19576" data-page_name="Spherical Activated Carbon｜ACC" data-page_type="menuPage">Spherical Activated Carbon</a></span></span></li> <li style="line-height: 1.75;"> <div class="menu-text ">--<span style="text-decoration: underline;"><span style="color: #236fa1;"><a style="color: #236fa1; text-decoration: underline;" href="resin-based-spherical-activated-carbon" target="_blank" rel="noopener" data-page_id="21460" data-page_name="Resin Based Spherical Activated Carbon" data-page_type="menuPage">Resin Based Spherical Activated Carbon</a></span></span></div> </li> </ul> <h2 style="line-height: 1.75;"><span style="font-size: 14pt; color: #045e14;"><strong>Conclusion</strong></span></h2> <p style="line-height: 1.75;"><span style="color: #000000;">In conclusion, phenolic resin-based spherical activated carbon offers significant advantages in terms of preparation and performance, making it highly promising for industrial development.</span></p> <hr /> <p style="line-height: 1.75;"><span style="color: #000000;">For more information on other types of activated carbon:</span></p> <ul> <li style="line-height: 1.75;"><span style="text-decoration: underline;"><span style="color: #236fa1; text-decoration: underline;"><a style="color: #236fa1; text-decoration: underline;" href="bamboo-based-activated-carbon" target="_blank" rel="noopener" data-page_id="19595" data-page_name="Bamboo Based Activated Carbon｜ACC" data-page_type="menuPage">Bamboo Based Activated Carbon</a></span></span></li> <li style="line-height: 1.75;"><span style="text-decoration: underline;"><span style="color: #236fa1; text-decoration: underline;"><a style="color: #236fa1; text-decoration: underline;" href="wood-based-activated-carbon" target="_blank" rel="noopener" data-page_id="19594" data-page_name="Wood Based Activated Carbon｜ACC" data-page_type="menuPage">Wood Based Activated Carbon</a></span></span></li> <li style="line-height: 1.75;"><span style="text-decoration: underline;"><span style="color: #236fa1; text-decoration: underline;"><a style="color: #236fa1; text-decoration: underline;" href="coconut-shell-based-activated-carbon" target="_blank" rel="noopener" data-page_id="19605" data-page_name="Coconut Shell Based Activated Carbon｜ACC" data-page_type="menuPage">Coconut Shell Based Activated Carbon</a></span></span></li> <li style="line-height: 1.75;"><span style="text-decoration: underline;"><span style="color: #236fa1; text-decoration: underline;"><a style="color: #236fa1; text-decoration: underline;" href="precious-metal-carrier-activated-carbon" target="_blank" rel="noopener" data-page_id="19582" data-page_name="Precious Metal Carrier Activated Carbon｜ACC" data-page_type="menuPage">Precious Metal Carrier Activated Carbon</a></span></span></li> </ul> <p style="line-height: 1.75;"> </p>